Comment by _ph_

It is the main reason you have to be careful with working with liquid nitrogen in closed rooms: the danger of displacing too much oxygen. While our breathing air consists of 80% nitrogen, when you evaporate large amounts of liquid nitrogen (like 10 liters in an instant) in a closed room, there is the danger of displacing oxygen to a dangerous level. Working with smaller amounts (like 1 liter) is quite safe though.