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Comment by czinck

5 years ago

> I don't think cats are to address greenhouse gasses; they're focused more on reducing pollutants that affect local air quality and human health.

I thought the same thing, but interestingly that's only kinda true. If anything, cats increase CO_2 as a desired end goal, because it's better to have CO_2 than CO or NO_x (or so the EPA has decided, I am no where near qualified to decide that). The issue with running too lean is that the reactions in the cat would rather use plain O_2 than NO_x, and so if you have too much O_2 (lean) you won't get rid of any of the NO_x [0]. Before looking into this I thought lean engines produced more NO_x because of higher cylinder temps or something like that (which might be true as well).

Cats not reducing NO_x when lean is essentially why Volkswagen (and practically every other manufacturer has been caught doing similar things to diesel engines) was cheating the test. Diesels have no throttle so they are (almost) always lean, typically very lean.

This does make me wonder, though, does running lean actually increase fuel efficiency? Obviously rich lowers fuel economy because not all the fuel burns, but assuming it all burns what does it matter if you have 1 gram of fuel to 15 grams of air in the cylinder, or 1 gram of fuel to 18 grams of air in the cylinder? You'll still get the same amount of energy, right?

[0] https://en.wikipedia.org/wiki/Catalytic_converter#Three-way