Comment by gene-h
1 year ago
And why wouldn't it work? Linear slide like mechanisms consisting of a silver surface and single molecule have been demonstrated[0]. The molecule only moved along rows of the silver surface. It was demonstrated to stay in one of these grooves up to 150 nm. A huge distance at this scale.
It can work (see my sibling comment) but it's tricky. The experiment you link was done under ultra-high vacuum and at low temperatures (below 7 K), using a quite exotic molecule which is, as I understand it, covered in halogens to combat the "sticky fingers" problem.
You seem to be knowledgeable about this topic. The reversible component designs in the article appear to presuppose a clock signal without much else said about it. I get that someone might be able to prototype an individual gate, but is the implementation of a practical clock distribution network at molecular scales reasonable to take for granted?
Not an expert, but would this count as molecular scale :)?
https://en.wikipedia.org/wiki/Chemical_clock
(This version can be done at home with halides imho: https://en.wikipedia.org/wiki/Iodine_clock_reaction)
To your question: I suppose all you need is for the halide moieties (Br) in your gates to also couple to the halide ions (Br clock?). The experiment you link was conducted at 7K for the benefit of being able to observe it with STM?
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I'm only acquainted with the basics of the topic, not really knowledgeable. It's an interesting question. I don't think the scale poses any problem—the smaller the scale is, the easier it is to distribute the clock—but there might be some interesting problems related to distributing the clock losslessly.
Not entirely.. terminal Br were also required to keep the molecule on the Silver tracks..
Those are some of the halogens I'm talking about. It's a little more polarizable than the covalently-bonded fluorine, so you get more of a van der Waals attraction, but still only a very weak one.