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Comment by delichon

4 hours ago

Thanks for the advice. I bought 30% vinegar on Amazon. The instructions are to add in a little dish soap. Do you think that will safely repel the dog when dry?

The soap is a surfactant to make the vinegar stick to the weed leaves for longer.

It's not necessary, but it probably lets you use a little less vinegar, so it's probably worthwhile. I don't add soap, I just spray straight 30% (agricultural) vinegar in the small set of areas where a torch would be dangerous.

Dried vinegar does not irritate dogs. They will avoid the area while it smells like pickles.

A better chemist than I will hopefully corroborate this, but I think that the strength of smell is directly correlated to the reactivity of the acid. So when the smell is mild (i.e. near the level of household vinegar (5%)), the risk to skin and mucous membranes is low-to-zero.

I don’t think there will be much left of the vinegar when dried. Acetic acid is much more volatile than water. If it’s dry, it means that it’s gone. And it has an unpleasant smell even at harmless concentrations, if it’s not quite dry yet.