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Comment by nine_k

13 hours ago

Helium has the second highest [1] specific heat capacity (after hydrogen); it's significantly higher than that of even water. It's damn efficient at cooling or heating. With that, it's chemically inert, unlike hydrogen or ammonia. There's no reasonable substitute.

[1]: https://en.wikipedia.org/wiki/Table_of_specific_heat_capacit... (Sort by the third column.)

Heat capacity is irrelevant -- argon and helium have exactly the same heat capacity per liter of gas, which would be the figure of merit in this context.

Heat conductivity, on the other hand, is an order of magnitude higher for helium, compared to argon, because its atoms are moving faster due to their lower mass.

When the gas is used for cooling, heat conductivity is important because it determines the conductivity through the boundary layer near surface, where the velocity of the flow drops to zero at the surface itself, and all the heat transport is through conduction rather than advection.

It's about the thermal conductivity.

Helium has 150mW/mK vs Argon ~18mW/mK so you can't replace it.

The only alternatives to Helium are Neon, which is 3x worse and much more expensive, and hydrogen. However, hydrogen is flammable so it's a very bad idea to use it in a fab which has extremely poisonous gases and needs a cleanroom environment. A fire would ruin your whole factory and kill your engineers.