Comment by rcxdude

from my point of view, ben_w definitely understand thermodynamics better than you. I'll point out that generally speaking radiative heat transfer from air is not particularly significant locally: it only tends to matter in the details when you're dealing with the whole atmosphere, which on average is a lot cooler. The transfer is also not blackbody radiation, so even then you can't really plug the air temperature into a radiative heat transfer calculation and expect a sensible result.