Strange crystals found inside wreckage from the first nuclear bomb test

3 months ago (scientificamerican.com)

> "a quasicrystal — a kind of matter scientists once thought impossible that challenges traditional ideas about how solids form"

Whenever I read a phrase about scientists observing something they thought was impossible ... I get really excited for scientists in that field! :-)

  • There's a wonderful book by one of the discoverers of quasicrystals, Paul Steinhardt, called "The second kind of impossible" which is a fantastic read and full of the excitement you alluded to. Very accessible and enjoyable.

  • Just a note, clathrates in general aren't rare or exotic at all, in fact methane clathrates are estimated in the million-cubic-km range. It's this specific type of clathrate, created under exotic circumstances, that's unusual.

What was special about the first nuclear test, rather than the thousands of others, at least hundreds of which were also in the Nevada desert?

Obviously it's historically significant, and the new forms of matter were first discovered there , so that's why trinitite is named after the site. But 80 years later, wouldn't we expect the other bomb sites to have just as many interesting chemical reactions?

> The clathrate’s “cage” shapes are 12-sided dodecahedrons and 14-sided tetrakaidecahedrons made of silicon atoms...

Totally OT but if "dodeca" means 12, why isn't 14 just "tetradeca"? What's the "kai" for?

  • For the same reason why in English 12 = twelve, but 14 = fourteen. Not all numerals are formed by the same rule.

    The correspondents of the -teen numbers in Greek were formed similarly with English, after the model of 14 = four and ten = "tetrakaideka".

    "Tetrakaideka" is a contracted form of 14, normally used in compound words. When "14" was an isolated word, it would have been "tettarakaideka" or "tessarakaideka". These are the forms for the neuter gender, the numeral "4" = "tettara" or "tessara" (depending on the dialect) was changed by declension for other genders and cases.

    In Ancient Greek numbers bigger than 20, the word "and" = "kai" was usually omitted, but then the bigger number was always the first like in "twenty-four". When "and" was inserted, then the order could also be inverse, like in "four-and-twenty".

  • Because the Greek word for 12 is something like "though-theka". And the word for 14 is "theka-tessera". Like most European languages, 11 and 12 are special, then it reverts to the "single digit - ten" or "ten - single digit" pattern.

    "kai" is "and" in Greek.

  • As the sibling comment already said "kai" (pronounced ke like in keg) just means "and". So it literally means 4 and 10 sides in greek. But I have often seen it written as τετραδεκάεδρο (tetradecahedron) in greek as well, so without the kai part. I'm not sure why it is 4 and 10 instead of 14 though. It would be more natural in greek that way (δεκατετράεδρο - decatetrahedron). Maybe it is for putting the distinctive part (4) first, or maybe it sounded more "poetic" like that to someone and then it stuck.

    • I think the three-and-ten, four-and-ten way of expressing numbers is primarily an ancient Greek thing. The modern numbers are expressed differently (δεκατέσσερα / dekatessara for fourteen, for example). In a lot of older European languages 11 and 12 behaved irregularly. You could argue that they do in English too (we don't have oneteen and twoteen).

      I haven't read of any particular reason for this, but I'd posit that numbers up to twelve were more commonly used in everyday life, so shorter, irregular forms were easier to use and remember. Much like many of the irregular verb forms in spoken language happened because they were so commonly used.

      The ancient Greek system also gave us triskaidekaphobia - the fear of the number 13.

      8 replies →

    • > "kai" (pronounced ke like in keg)

      Ancient Greek spans several centuries of sound shifts and many dialects. It cannot easily be simplified into one specific pronunciation, particularly not one that is based on your specific dialect of English. Wiktionary has /kǎi̯/, /ˈkɛ/, /ˈcɛ/ and /ˈce/ for "καὶ".

      1 reply →

> The only other known naturally forming quasicrystal was found inside meteorite fragments

Does it really count as "naturally forming" if we had to artificially construct and detonate a nuke during a carefully conducted experiment to create this one?

  • Well, it's more natural than something like a lab diamond. This one forms naturally given unnaturally created, but not completely implausible, conditions. There is a big difference between "we blew up rocks and they formed this mineral" and "we treated rocks with X acid and Y acid and then carefully annealed them under extreme pressure and they formed this mineral"

  • How do we know the quasicrystals in the meteorite fragments are naturally occurring, and weren't created by nuclear detonations on an alien planet, then blasted off into space when an asteroid hit the site? Or perhaps the nuclear explosion was tested on an asteroid rather than a planet.

  • We’re a product of nature, it’s mistaken to believe we are above nature or that nuclear weapons aren’t also part of nature.

    We’re also very much dependent on nature and natural forces.

    So everything we do is, even if many steps removed, still an act of nature.

    • With the influence of humans: artificial.

      Without the influence of humans: natural.

      There’s a useful definition for you. Otherwise according to your definition the term “natural” is completely meaningless and serves no purpose.

      7 replies →

    • Diamonds are also product of nature, but when we grow them in a lab they aren't often considered to be "naturally formed". It's just that the lab we used in this instance was part of the Jornada del Muerto.

      3 replies →

One language usage question, and one content question:

"Melted sand"?? Isn't it "molten sand"? Is my hunch completely wrong, or is the author not a native speaker? Neither am I, but melted sand sounds so weird to my ears.

    This all happened in a matter of seconds, so atoms didn’t have time to arrange into stable structures,[...]

Isn't seconds kinda like ages at that scale? Atoms needing longer than seconds to arrange under super high pressure sounds also dubious? But I am no expert in that area.

  • To my ears “Molten” would imply that the sand is currently in liquid form. The sense ”melted” is used here, as having been melted, seems right. You melt sand to get molten sand, right?

  • "Molten" to me implies it is still liquid. Molten salt reactors, molten magma from a volcano, molten sand, molten steel, dipping something into molten cheese. All fluid.

    If I was to nitpick, "melted" is kind of inaccurate and not entirely natural in this context. Technically, molten sand is also melted sand, because that's how you get it to that state? Usually, you'd hear about solidified magma, crystalized sand, cast iron, air-cast steel, unevenly settled corium... to make a better point on how it turned back into a solid and what to expect from it - something like "The molten sand crystalized into an unusual structure" would be clearer.

    I'd usually rather hear "melted" if it is important to note that this had a phase change and back. Plastic on an electrical device may look melted, indicating heat. A hardened steel part may look melted, which may damage the hardening. Rubber on a hydraulic line may look melted, also indicating heat. A plastic container looking melted in the context of chemicals may indicate some compromise.

    Now the words sound weird in my head. Thank you.

  • It’s being used as a participial adjective here. I don’t think there’s much semantic nuance in the distinction between “melted” and “molten.” It comes down to common usage. “Molten sand” sounds more suitable to my ears, but “melted butter” also sounds better than “molten butter.” Odd, I think it’s part of a trend to replace the use of the past participle in some adjectival contexts. Maybe melted/molten is just an incomplete transition.

  • I think it's "molten" while it is still liquid but not once it crystalizes; at that point it's "melted"

  • Think of dropping a water balloon onto a pin. It pops instantly, but the water (like the temperature and overpressure) takes a while to dissipate into a puddle.

Sounds like the plot of a B movie...

While the news is interesting in itself, I found the lack of illustrations disappointing.

When discussing new novel molecular structures, one would think providing a concrete visuals of what they look like more interesting than human-scale photos of materials containing them?