Comment by cauch

No.

OP says: LLMs never think when not invoked.

What you said: I have example where, sometimes, human think when invoked.

That's the difference: human brains are intrinsically different because they are built to be able to think without being invoked, even if there are situations where they think when invoked.

There are tons of obvious examples of human thinking without being invoked. Just take a bath and you will see :)