Comment by jcranmer

The list of supported GCC architectures is here: https://gcc.gnu.org/backends.html

LLVM doesn't have an equivalent annotated list, but it is missing alpha, bfin, c6x, fr30, frv, gcn, h8300, ia64 (aka Itanium), lm32, m32c, m32r, mcore, mep, microblaze, mmix, mn10300, moxie, nds32, nios2, pa (aka PA-RISC), pdp11, pru, rl78, rs6000, rx, sh (aka SuperH), storm16, v850, vax, and visium. For its part, LLVM does have some targets that GCC doesn't have (mostly related to GPU compilation).

The "big" targets that GCC has that LLVM lacks are Alpha, Itanium, PA-RISC, and SuperH, with Itanium being sufficiently weird that it's pretty firmly in the "fuck this" category from a maintainer's perspective, and people are actively ripping out support for it.